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Organometallic Chemistry Made Easy Book For CSIR-NET, IIT-JAM, GATE & M.Sc Aspirants. All CSIR-NET, GATE, IIT JAM 10 year Previous Year Papers With Solution.
Contents
I · F O U N D A T IO NS ..................................................................... 1
1. Introduction, History and Nomenclature........................................................ 2
2. The 18-Electron Rule and Electron Counting................................................. 12
3. A Field Guide to Organometallic Ligands...................................................... 24
I I · T H E M E T A L C A R B O N Y L S TO R Y ............................................... 3 6
4. Bonding in Metal Carbonyls......................................................................... 37
5. Preparation, Properties and Reactions of Metal Carbonyls............................ 47
I I I · ST R U C T U R E , D Y N A M I C S A N D R E A C T I V I T Y ............................... 5 5
6. Ferrocene and the Sandwich Family............................................................. 56
7. Fluxionality and Spectroscopic Characterisation ........................................... 74
8. Elementary Reactions of Organometallic Complexes .................................... 79
I V · C A T A L Y S I S ....................................................................... 9 9
9. Homogeneous Catalysis ............................................................................ 100
V · A D V A N C E D T O P I C S ............................................................ 15 0
10. Stability of Organometallic Compounds ................................................... 151
11. Metal Clusters, Wade’s Rules and Metal–Metal Bonds ............................. 156
12. The Isolobal Analogy ............................................................................... 189
V I · R A P I D R E V I S I O N A N D P R A C T I C E .......................................... 197
13. Rapid Revision Kit: Flashcards and Summary Tables.................................. 198
14. Topic-Wise Special Question Set 2 ........................................................... 212
15. Previous Year Questions: CSIR-NET, GATE And IIT-JAM ............................. 219
